Final report for the Light Water Breeder Reactor proof-of-breeding analytical support project

The technology of breeding uranium-233 from thorium-232 in a light water reactor is being developed and evaluated by the Westinghouse Bettis Atomic Power Laboratory (BAPL) through operation and examination of the Shippingport Light Water Breeder Reactor (LWBR). Bettis is determining the end-of-life (EOL) inventory of fissile uranium in the LWBR core by nondestructive assay of a statistical sample comprising approximately 500 EOL fuel rods. This determination is being made with an irradiated-fuel assay gauge based on neutron interrogation and detection of delayed neutrons from each rod. The EOL fissile inventory will be compared with the beginning-of-life fissile loading of the LWBR to determine the extent of breeding. In support of the BAPL proof-of-breeding (POB) effort, Argonne National Laboratory (ANL) carried out destructive physical, chemical, and radiometric analyses on 17 EOL LWBR fuel rods that were previously assayed with the nondestructive gauge. The ANL work included measurements on the intact rods; shearing of the rods into pre-designated contiguous segments; separate dissolution of each of the more than 150 segments; and analysis of the dissolver solutions to determine each segment's uranium content, uranium isotopic composition, and loading of selected fission products. This report describes the facilities in which this work was carried out, details operations involved in processing each rod, and presents a comprehensive discussion of uncertainties associated with each result of the ANL measurements.