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Synthetische Verwendung von Epoxynitronen. II. Synthese von Steroid-?-methyliden-?-lactonen

Authors :
Walter Graf
Martin Riediker
Source :
Helvetica Chimica Acta. 62:1586-1602
Publication Year :
1979
Publisher :
Wiley, 1979.

Abstract

Synthetic application of epoxynitrones. II. Syntheses of steroidal α-methylidene-γ-lactones This communication describes the application of the epoxynitrone/CF3SO3SiR3 1,2-oxazine annelation-reaction [1] to the syntheses of steroidal α-methylidene-γ-lactones from olefines, e.g.12 14a/b 16a/b 18a/b 20 22(Scheme 2).

Details

ISSN :
15222675 and 0018019X
Volume :
62
Database :
OpenAIRE
Journal :
Helvetica Chimica Acta
Accession number :
edsair.doi...........0eb2ab0feaf35f1dc12cb73ee5dc17bb
Full Text :
https://doi.org/10.1002/hlca.19790620524