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GREEN SYNTHESIS OF 2-(1H-PYRAZOL-5-yl) ANILINE AS A CORROSION INHIBITOR OF ALUMINIUM-2014 ALLOY IN 1.0 MOLAR HCl SOLUTION

Authors :
null G. Nataraja
B. M Praveen
R. D Pruthviraj
N. Ganesh Yallappa
M. V. Santhosh Kumar
Source :
RASAYAN Journal of Chemistry. :143-149
Publication Year :
2022
Publisher :
Rasayan Journal of Chemistry, 2022.

Abstract

We worked on the synthesis of an organic molecule, i.e., 2-(1H-pyrazol-5-yl) aniline by the microwave method via Amino Cinnamaldehyde and hydrated hydrazine in the presence of ethanol solvent and studied its Corrosion inhibition property on Aluminium-2014 alloy in the 1Molar Hydrochloric acid solution at 25⁰C and 35⁰C temperatures. The SEM micrographs are obtained and examined the surface nature of inhibitor-treated and untreated surfaces. It reveals that the 2-(1H-pyrazol-5-yl) aniline treated surface has more tendency of prevention to corrosion than the free Aluminium 2014 alloy. The potentiodynamic values revealed that Aluminium-2014 alloy possessing different concentrations exhibit a higher tendency to prevent corrosion in 1M Hydrochloric acid solution at 25⁰C and 35⁰C temperatures. We studied Tafel polarization and electrochemical impedance at different concentrations at 25⁰C and 35⁰C. The rate of adsorption increases with the inhibitor concentrations.

Details

ISSN :
09760083 and 09741496
Database :
OpenAIRE
Journal :
RASAYAN Journal of Chemistry
Accession number :
edsair.doi...........0eae499fb48e54258b21bf5f1ca76736
Full Text :
https://doi.org/10.31788/rjc.2022.1558046