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Novel microporous carbon prepared from discarded clothes as host materials for high performance lithium-sulfur battery

Authors :
Yanli Wang
Menghua Chen
Lihao Wang
Ying Huang
Xiaogang Gao
Xu Sun
Source :
Materials Letters. 232:122-125
Publication Year :
2018
Publisher :
Elsevier BV, 2018.

Abstract

Novel microporous carbon materials (DCMC) with excellent electron conductivity and ultrahigh surface area (1896.9 m 2 g −1 ) are successfully prepared from discarded clothes. The porous carbon-encapsulated sulfur composites were synthesized by a feasible melting process and used as host materials for lithium sulfur batteries. Because of the unique microporous, ultrahigh surface area and irregular wrinkled surface coexisting structure, the resulting microporous carbon/sulfur (DCMC/S) composite cathode possesses a good rate capability and long-term cycling performance. The initial discharge capacity of the DCMC2/S composite electrode with 74.3 wt% sulfur content is 1082.6 mAh g −1 at a current rate of 0.2 C. At a higher current rate of 1 C, it possesses excellent cyclic performance and retained a capacity of 422.8 mAh g −1 after 500 cycles with a low capacity fading rate of 0.11% per cycle. The coulombic efficiency remains over 98% during cycling.

Details

ISSN :
0167577X
Volume :
232
Database :
OpenAIRE
Journal :
Materials Letters
Accession number :
edsair.doi...........0dae247fc1fc9df3b6ba4b8ebb3fae94