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A demonstration of aldehyde-lactol tautomerism in gossypol by1H and13C NMR spectroscopy
- Source :
- Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 28:938-944
- Publication Year :
- 1979
- Publisher :
- Springer Science and Business Media LLC, 1979.
-
Abstract
- 1. The existence of a tautomeric equilibrium between the aldehyde and lactol forms gossypol has, for the first time, been demonstrated through NMR spectroscopy. In DMSO, gossypol exists primarily in the lactol form, and primarily in the aldehyde form in acids, bases, and inert solvents. 2. The method of preparation of the ethers of this compound determines the form of the product obtained.
Details
- ISSN :
- 15739171 and 05685230
- Volume :
- 28
- Database :
- OpenAIRE
- Journal :
- Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
- Accession number :
- edsair.doi...........0c3b8167890cdce5720c23583075d52f