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Superior Base Catalysis of Group 5 Hexametalates [M6O19]8– (M = Ta, Nb) over Group 6 Hexametalates [M6O19]2– (M = Mo, W)

Authors :
Naoto Sasaki
Tatsuya Tsukuda
Seiji Yamazoe
Shun Hayashi
Source :
The Journal of Physical Chemistry C. 122:29398-29404
Publication Year :
2018
Publisher :
American Chemical Society (ACS), 2018.

Abstract

Bronsted and Lewis base catalysis of hexametalate clusters of group 5 metals [M(V)6O19]8– (M(V) = Ta, Nb) and group 6 metals [M(VI)6O19]2– (M(VI) = Mo, W) was studied using Knoevenagel condensation...

Details

ISSN :
19327455 and 19327447
Volume :
122
Database :
OpenAIRE
Journal :
The Journal of Physical Chemistry C
Accession number :
edsair.doi...........0b9b2176f69183522282cfcdec796cb4