ChemInform Abstract: Further Insight into the Photochemical Behavior of Aromatic γ,δ-Epoxy Ketones: A New Approach for Synthesis of 4-Methyleneisochromanols

Authors :: Bing Li
Chao Yang
Weitao Xia
Wujiong Xia
Source :: ChemInform. 47
Publication Year :: 2016
Publisher :: Wiley, 2016.
Abstract: The photochemical behavior of methyl-substituted aromatic γ,δ-epoxy ketones was investigated by irradiation with a 500 W high-pressure mercury lamp in benzene which led to the formation of 4-methyleneisochromanols through δ-hydrogen abstraction–epoxy rearrangement–1,5-biradical cyclization reactions.

Subjects :: Mercury-vapor lamp
chemistry.chemical_compound
Chemistry
law
visual_art
visual_art.visual_art_medium
General Medicine
Epoxy
Irradiation
Photochemistry
Benzene
law.invention

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