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Effect of transition metal composition on electrochemical performance of nickel-manganese-based lithium-rich layer-structured cathode materials in lithium-ion batteries
- Source :
- Journal of Solid State Chemistry. 249:80-86
- Publication Year :
- 2017
- Publisher :
- Elsevier BV, 2017.
-
Abstract
- To evaluate the effect of transition metal composition on the electrochemical properties of Li-rich layer-structured cathode materials, Li 1.2 Ni x Mn 0.8− x O 2 ( x =0.2, 0.25, 0.3, and 0.4) were synthesized, and their electrochemical properties were investigated. As nickel content x increased in Li 1.2 Ni x Mn 0.8− x O 2 ( x =0.2, 0.25, 0.3, and 0.4), charge-discharge capacities at a low C-rate (0.05 C) decreased. The results obtained by dQ/dV curves indicate that, as the nickel content increased, the discharge capacity below 3.6 V greatly decreased, but that above 3.6 V increased. As the C-rate of the discharge process increased, the discharge reaction of Li 1.2 Ni x Mn 0.8− x O 2 ( x =0.2) below 3.6 V greatly decreased. In contrast, that above 3.6 V slightly decreased. This indicates that the discharge reaction above 3.6 V exhibits higher rate performance than that below 3.6 V. For the high-nickel-content cathodes, the ratio of the discharge capacity above 3.6 V to the total discharge capacity was high. Therefore, they exhibited high rate performance.
- Subjects :
- Materials science
020209 energy
Inorganic chemistry
Analytical chemistry
chemistry.chemical_element
02 engineering and technology
Manganese
Electrochemistry
Lithium-ion battery
Ion
law.invention
Inorganic Chemistry
Transition metal
law
0202 electrical engineering, electronic engineering, information engineering
Materials Chemistry
Physical and Theoretical Chemistry
021001 nanoscience & nanotechnology
Condensed Matter Physics
Cathode
Electronic, Optical and Magnetic Materials
Nickel
chemistry
Ceramics and Composites
Lithium
0210 nano-technology
Subjects
Details
- ISSN :
- 00224596
- Volume :
- 249
- Database :
- OpenAIRE
- Journal :
- Journal of Solid State Chemistry
- Accession number :
- edsair.doi...........0965ba4a7fc86d2e953691ecb8550a0b