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FeOOH–CoS composite catalyst with high catalytic performances for oxygen evolution reaction at high current density

Authors :
Meng Zhu
Yuan-Yuan Feng
Hua-Shuai Hu
Jing Zhao
Gao Deng
Xiang-Yu Wang
Source :
International Journal of Hydrogen Energy. 46:37333-37339
Publication Year :
2021
Publisher :
Elsevier BV, 2021.

Abstract

Water electrolysis is an efficient approach for high-purity hydrogen production. However, the anodic sluggish oxygen evolution reaction (OER) always needs high overpotential and thus brings about superfluous electricity cost of water electrolysis. Therefore, exploiting highly efficient OER electrocatalysts with small overpotential especially at high current density will undoubtedly boost the development of industrial water electrolysis. Herein, we used a simple hydrothermal method to prepare a novel FeOOH–CoS nanocomposite on nickel foam (NF). The as-prepared FeOOH–CoS/NF catalyst displays an excellent OER performance with extremely low overpotentials of 306 and 329 mV at 500 and 1000 mA cm−2 in 1.0 M KOH, respectively. In addition, the FeOOH–CoS/NF catalyst can maintain excellent catalytic stability for more than 50 h, and the OER catalytic activity shows almost no attenuation no matter after 1000 repeated CV cycles or 50 h of stability test. The high catalytic activity and stability have exceeded most non-noble metal electrocatalysts reported in literature, which makes the FeOOH–CoS/NF composite catalyst have promising applications in the industrial water electrolysis.

Details

ISSN :
03603199
Volume :
46
Database :
OpenAIRE
Journal :
International Journal of Hydrogen Energy
Accession number :
edsair.doi...........08e6bbef32cda952eb0a679447c5b7b7
Full Text :
https://doi.org/10.1016/j.ijhydene.2021.09.015