ChemInform Abstract: Asymmetric Catalysis of Carbonyl-Ene and Aldol Reactions with Fluoral by Chiral Binaphthol-Derived Titanium Complex

Authors :: Tomoko Yajima
Tsuyoshi Takasaki
Koichi Mikami
Tadafumi Uchimaru
Masahiro Terada
Masamichi Maruta
Satoru Matsukawa
Source :: ChemInform. 27
Publication Year :: 2010
Publisher :: Wiley, 2010.
Abstract: The chiral titanium complex-catalyzed ene-type reaction and the Mukaiyama aldol reaction with fluoral are shown to serve as an efficient route to the enantioselective and diastercoselective synthesis of CF 3 -substituted components of biological and synthetic importance.

Subjects :: chemistry
Aldol reaction
Enantioselective synthesis
chemistry.chemical_element
Organic chemistry
General Medicine
Ene reaction
Titanium

Full Text Access

Tools