ChemInform Abstract: A Convenient Synthesis of Tertiary Carbinamines via N-Aluminum Ketimines

Reaction of N-unsubstituted ketimines with organoaluminum reagents prepared from allylic and propargylic halides, allows to prepare, in good yields, tertiary carbinamines with three different groups (phenyl, alkyl and α-unsaturated group) on the tertiary carbon center.