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Chemoselective Addition of Hydrazine to δ‐Keto Esters and Dimethylformamide‐Mediated Deesterification

Authors :
Sivaperuman Saravanan
Shanmugam Muthusubramanian
Vellaisamy Sridharan
Source :
Synthetic Communications. 36:849-858
Publication Year :
2006
Publisher :
Informa UK Limited, 2006.

Abstract

The chemoselective reaction of hydrazine on the ketone rather than the ester in a gem diester system with a γ‐keto group by hydrazinium sulfate and a tandem deesterification of one of the esters in this system by N,N‐dimethylformamide are reported.

Details

ISSN :
15322432 and 00397911
Volume :
36
Database :
OpenAIRE
Journal :
Synthetic Communications
Accession number :
edsair.doi...........07e84b528436a9350754ebdd06cac44b
Full Text :
https://doi.org/10.1080/00397910500464319