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New Single Ion Conducting Blend Based on PEO and PA-LiTFSI
- Source :
- Electrochimica Acta. 255:48-54
- Publication Year :
- 2017
- Publisher :
- Elsevier BV, 2017.
-
Abstract
- New synthesis route of polysalt with single ion conductivity based on functionalization of polyacrylic acid is reported for all solid state lithium metal batteries. Poly[(trifluoromethyl)sulfonyl acrylamide] PA–LiTFSI was synthesized in two steps reaction. The degree of functionalization of the polymer backbone by anion of lithium salt bis(trifluoromethane)sulfonimide (LiTFSI) was confirmed by ICP analysis. An ionic conductivity equal 1,77 10 −5 S cm −1 at 80 °C of polysalt blended with PEO is reported. Easy process-able polysalt blended with PEO exhibits good mechanical properties and high transference number.
- Subjects :
- chemistry.chemical_classification
Sulfonyl
Materials science
Trifluoromethyl
General Chemical Engineering
Polyacrylic acid
chemistry.chemical_element
02 engineering and technology
Polymer
Conductivity
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
0104 chemical sciences
chemistry.chemical_compound
chemistry
Polymer chemistry
Electrochemistry
Ionic conductivity
Surface modification
Lithium
0210 nano-technology
Subjects
Details
- ISSN :
- 00134686
- Volume :
- 255
- Database :
- OpenAIRE
- Journal :
- Electrochimica Acta
- Accession number :
- edsair.doi...........075c9c235f62467cba2b8ae4f4b64ce9
- Full Text :
- https://doi.org/10.1016/j.electacta.2017.09.139