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New Single Ion Conducting Blend Based on PEO and PA-LiTFSI

Authors :
Michal Piszcz
Jörg Thielen
Michel Armand
Chunmei Li
Uxue Oteo
Oihane Garcia-Calvo
Lide M. Rodriguez-Martinez
Juan Miguel López del Amo
Hicham Ben Youcef
Nerea Lago
Source :
Electrochimica Acta. 255:48-54
Publication Year :
2017
Publisher :
Elsevier BV, 2017.

Abstract

New synthesis route of polysalt with single ion conductivity based on functionalization of polyacrylic acid is reported for all solid state lithium metal batteries. Poly[(trifluoromethyl)sulfonyl acrylamide] PA–LiTFSI was synthesized in two steps reaction. The degree of functionalization of the polymer backbone by anion of lithium salt bis(trifluoromethane)sulfonimide (LiTFSI) was confirmed by ICP analysis. An ionic conductivity equal 1,77 10 −5 S cm −1 at 80 °C of polysalt blended with PEO is reported. Easy process-able polysalt blended with PEO exhibits good mechanical properties and high transference number.

Details

ISSN :
00134686
Volume :
255
Database :
OpenAIRE
Journal :
Electrochimica Acta
Accession number :
edsair.doi...........075c9c235f62467cba2b8ae4f4b64ce9
Full Text :
https://doi.org/10.1016/j.electacta.2017.09.139