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The preparation of lithium organocuprates from various Cu(I) salts

Authors :
Gary Dabbagh
Charles P. Gibson
Steven H. Bertz
Source :
Tetrahedron Letters. 28:4251-4254
Publication Year :
1987
Publisher :
Elsevier BV, 1987.

Abstract

Various Cu(I) salts have been tested as precursors for organocuprates in side-by-side comparisons under controlled conditions. CuCN and CuBr·SMe2 appear to be superior to CuI, CuBr, and CuCl. CuSCN and CuOTf are also good precursors in some circumstances.

Details

ISSN :
00404039
Volume :
28
Database :
OpenAIRE
Journal :
Tetrahedron Letters
Accession number :
edsair.doi...........064deb19caf8e9bcd15f205b5c7ddae1
Full Text :
https://doi.org/10.1016/s0040-4039(00)96477-3