Unconventional magnetic ferroelectricity in the quadruple perovskite NaMn7O12

By means of magnetic, specific heat, and pyroelectric measurements, we report on magnetic ferroelectricity in the quadruple perovskite $\mathrm{Na}{\mathrm{Mn}}_{7}{\mathrm{O}}_{12}$, characterized by a canted antiferromagnetic (AFM) CE structure. Surprisingly, ferroelectricity is concomitant to a dramatic broadening of the magnetic hysteresis loop, well below the AFM ordering temperature. This unconventional behavior shows that the formation of ferroelectric domains is induced by the symmetric exchange interaction in the local scale, e.g., at magnetic domain boundaries or defects. The value of electric polarization, $P=0.027\phantom{\rule{4pt}{0ex}}\ensuremath{\mu}\mathrm{C}\phantom{\rule{0.16em}{0ex}}{\mathrm{cm}}^{\ensuremath{-}2}$, measured in polycrystalline samples is comparatively large as compared to other magnetic multiferroics, suggesting that the above scenario is promising indeed for the rational design of practical multiferroic materials.