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ChemInform Abstract: Expedient Synthesis of Complex γ-Butyrolactones from 5-(1-Arylalkylidene) Meldrum′s Acids via Sequential Conjugate Alkynylation/Ag(I)-Catalyzed Lactonization

Authors :
Siawash Ahmar
Eric Fillion
Source :
ChemInform. 46
Publication Year :
2015
Publisher :
Wiley, 2015.

Abstract

The conjugate addition reaction of metal alkynylides to Meldrum′s acids gives access to derivatives (III) and (VI) having a propargylic all-carbon quaternary center.

Details

ISSN :
09317597
Volume :
46
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........04cd590ec7ac98de1dec0e2ad1d94e0a
Full Text :
https://doi.org/10.1002/chin.201517138