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C(sp3)–H bond functionalization with styrenes via hydrogen-atom transfer to an aqueous hydroxyl radical under photocatalysis
- Source :
- Green Chemistry. 23:3575-3580
- Publication Year :
- 2021
- Publisher :
- Royal Society of Chemistry (RSC), 2021.
-
Abstract
- The redox-neutral addition of α-C–H bonds of acetonitrile and acetone to styrenes was enabled via the hydrogen-atom transfer from relatively acidic and water-miscible C(sp3)–H bonds to an aqueous hydroxyl radical generated cleanly and iteratively by the oxidation of water under silver-nanoparticle-loaded titania photocatalysis without using stoichiometric oxidation agents.
Details
- ISSN :
- 14639270 and 14639262
- Volume :
- 23
- Database :
- OpenAIRE
- Journal :
- Green Chemistry
- Accession number :
- edsair.doi...........0281fff814fdbd78fcbe67881202de5e