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Enthalpies and Heat Capacities of Ethyl Acetate Solutions in Water and in Several Organic Solvents at 298–318 K

Authors :
Andrey V. Kustov
Nataliya L. Smirnova
Olga A. Antonova
Source :
Journal of Solution Chemistry. 41:1008-1012
Publication Year :
2012
Publisher :
Springer Science and Business Media LLC, 2012.

Abstract

The enthalpies of solution of ethylacetate (EtOAc) in water, octane and 1-octanol (OctOH) were measured at 298, 308 and 318 K using a precise isoperibol calorimeter. The standard enthalpies and heat capacities of these non-electrolyte solution were computed and compared with the previously obtained ΔsolH∘ and \(\Delta C_{p}^{\circ}\) values in N,N-dimethylformamide (DMF). Partial molal heat capacities of EtOAc in water and in organic solvents were calculated and compared with the available literature values.

Details

ISSN :
15728927 and 00959782
Volume :
41
Database :
OpenAIRE
Journal :
Journal of Solution Chemistry
Accession number :
edsair.doi...........027a30802a3aac9356a46dbbc801ce0d
Full Text :
https://doi.org/10.1007/s10953-012-9841-4