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Complexes of Dichlorobis(Cyclopentadienyl)Titanium(IV) with N-(Aryl)-2-Mercaptoacetamides

Authors :
Ram Sharan
Y. Singh
Ramesh N. Kapoor
Source :
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 16:1225-1235
Publication Year :
1986
Publisher :
Informa UK Limited, 1986.

Abstract

Bis(cyclopentadienyl)titanium(IV)mercaptoacetamide derivatives of the type Cp2Ti(MA)Cl and Cp2Ti(MA)2 (Cp = cyclopentadienyl and MAH [dbnd] N-(aryl)-2-mercapto-acetamide; aryl = phenyl, o-tolyl, m-tolyl, p-tolyl or α-naphthyl) have been prepared from the reactions of dichlorobis(cyclopentadienyl)titanium(IV) (Cp2TiCl2) with various mercaptoacetamides in tetrahydrofuran (THF) at room temperature in the presence of triethylamine (Et3N). These new mercaptoacetamide derivatives have been characterized by their elemental analyses, electrical conductance, IR, 1H NMR and electronic spectral data.

Details

ISSN :
15322440 and 00945714
Volume :
16
Database :
OpenAIRE
Journal :
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Accession number :
edsair.doi...........01fb58f4c2072eea82b78620d01f262e