SOME FEATURES OF THE REDUCTION OF POLY(METHYLENE SULFIDES) AND POLY(METHYLENE POLYSULFIDES)

Authors :: Terje A. Skotheim
N. V. Russavskaya
Ol'ga Alekminskaya
G. F. Myachina
S. A. Korzhova
E. N. Sukhomazova
Deryagina Eleonora N
Boris A. Trofimov
Source :: Phosphorus, Sulfur, and Silicon and the Related Elements. 162:51-63
Publication Year :: 2000
Publisher :: Informa UK Limited, 2000.
Abstract: The reductive destruction of poly(methylene sulfides) and poly(methylene polysulfides) in the system hydrazine hydrate - NaOH at 70–1 15°C involves cleavage of the C-S bond and the formation of sulfide, disulfide and trisulfide anions. Nitrogen and methane are main gaseous products of reduction. The reduction of C-S bonds in these polymers is proven by electrochemical methods.

Subjects :: chemistry.chemical_classification
Sulfide
Organic Chemistry
Hydrazine
chemistry.chemical_element
Polymer
Photochemistry
Electrochemistry
Biochemistry
Nitrogen
Inorganic Chemistry
chemistry.chemical_compound
chemistry
Polymer chemistry
Methylene
Cyclic voltammetry
Hydrate

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