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In situ EXAFS study of Ru-containing electrocatalysts of oxygen reduction

Authors :
Elena R. Savinova
I.V Malakhov
Dmitry I. Kochubey
Nicolas Alonso-Vante
S. G. Nikitenko
Source :
Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment. 448:323-326
Publication Year :
2000
Publisher :
Elsevier BV, 2000.

Abstract

The series of Ru chalcogenide compounds is obtained by varying the nature of the chalcogen with the transition metal (Ru) matrix. The EXAFS technique reveals that the electrocatalytic centre is Ru in a cluster matrix. Furthermore, a reversible change in the structure of the active centre as a function of the applied electrode potential appears.

Details

ISSN :
01689002
Volume :
448
Database :
OpenAIRE
Journal :
Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment
Accession number :
edsair.doi...........00dd7abd792577ce4671115966868783
Full Text :
https://doi.org/10.1016/s0168-9002(99)00719-6