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Co nanoparticles supported 3D structure for catalytic H2 production

Authors :
Xianxian Li
Guanbo Huang
Chunjuan Gao
Haixia Qiu
Mingyi Tang
Source :
Materials Chemistry and Physics. 191:6-12
Publication Year :
2017
Publisher :
Elsevier BV, 2017.

Abstract

Cobalt nanoparticles supported elastic foam (Co-F) was prepared by coating commercial polyurethane foam with cobalt nanoparticle loaded hybrids (Co/rGO). The Co-F was applied to catalyze hydrolysis reaction of sodium borohydride to produce hydrogen gas. Co-F has large surface area and interconnected pores, so it showed outstanding activity in catalyzing the hydrolysis reaction and achieved a hydrogen production rate of 33.2 mL·min−1. The conditions for Co/rGO and Co-F preparation as well as reaction conditions like the reaction temperature, the concentration of NaBH4 and pH value all affected the catalytic hydrolysis of NaBH4. The Co-F could be easily recovered by taking out, pressing and rinsing in distilled water, and it exhibited almost unfaded catalytic activity in the reusage. The unique properties will make Co-F potential applications in catalytically chemical reactions.

Details

ISSN :
02540584
Volume :
191
Database :
OpenAIRE
Journal :
Materials Chemistry and Physics
Accession number :
edsair.doi...........00a497a5cbc9ba37dfd2bb4595189448
Full Text :
https://doi.org/10.1016/j.matchemphys.2017.01.014