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Co nanoparticles supported 3D structure for catalytic H2 production
- Source :
- Materials Chemistry and Physics. 191:6-12
- Publication Year :
- 2017
- Publisher :
- Elsevier BV, 2017.
-
Abstract
- Cobalt nanoparticles supported elastic foam (Co-F) was prepared by coating commercial polyurethane foam with cobalt nanoparticle loaded hybrids (Co/rGO). The Co-F was applied to catalyze hydrolysis reaction of sodium borohydride to produce hydrogen gas. Co-F has large surface area and interconnected pores, so it showed outstanding activity in catalyzing the hydrolysis reaction and achieved a hydrogen production rate of 33.2 mL·min−1. The conditions for Co/rGO and Co-F preparation as well as reaction conditions like the reaction temperature, the concentration of NaBH4 and pH value all affected the catalytic hydrolysis of NaBH4. The Co-F could be easily recovered by taking out, pressing and rinsing in distilled water, and it exhibited almost unfaded catalytic activity in the reusage. The unique properties will make Co-F potential applications in catalytically chemical reactions.
- Subjects :
- Materials science
Hydrogen
Inorganic chemistry
chemistry.chemical_element
Nanoparticle
02 engineering and technology
010402 general chemistry
021001 nanoscience & nanotechnology
Condensed Matter Physics
01 natural sciences
Chemical reaction
0104 chemical sciences
Catalysis
Sodium borohydride
chemistry.chemical_compound
Hydrolysis
chemistry
Distilled water
Chemical engineering
General Materials Science
0210 nano-technology
Cobalt
Subjects
Details
- ISSN :
- 02540584
- Volume :
- 191
- Database :
- OpenAIRE
- Journal :
- Materials Chemistry and Physics
- Accession number :
- edsair.doi...........00a497a5cbc9ba37dfd2bb4595189448
- Full Text :
- https://doi.org/10.1016/j.matchemphys.2017.01.014