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Cation Extraction Process in Bilayer Cyanide Film as Investigated by Depth-Resolved X-ray Absorption Spectroscopy
- Source :
- Japanese Journal of Applied Physics. 50:125802
- Publication Year :
- 2011
- Publisher :
- IOP Publishing, 2011.
-
Abstract
- The cation extraction process in the bilayer cyanide film with an epitaxial interface, Na0.84-y Co2+[Fe y 3+Fe1-y 2+(CN)6]0.713.8H2O (NCF71)/Na1.60-x (Co x 3+Co1-x 2+)[Fe2+(CN)6]0.902.8H2O (NCF90), was investigated by depth-resolved X-ray absorption spectroscopy. Assuming stepwise depth (z) distributions of Co3+ and Fe3+, we estimated the step depths, d Co and d Fe, and concentrations, δCo and δFe, of the respective ions against the average quantity (δav) of cation extraction. The Na+ extraction was found to be dominant in the NCF90 surface layer, consistent with the lower redox potential in the NCF90 layer. We found that the magnitude of d Fe (∼600 nm) is much deeper than the actual depth (d = 200 nm) of the NCF71/NCF90 interface, and interpreted the behavior in terms of the redox interaction in the vicinity of the interface.
Details
- ISSN :
- 13474065 and 00214922
- Volume :
- 50
- Database :
- OpenAIRE
- Journal :
- Japanese Journal of Applied Physics
- Accession number :
- edsair.doi...........005f1f57acdb377d49cf949a773a4a36