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A New and Efficient Catalytic Isomerization of cis- and trans-Epoxides

Authors :
Ching‐Yu Lo
Rai-Shung Liu
Sitaram Pal
Arjan Odedra
Source :
ChemInform. 34
Publication Year :
2003
Publisher :
Wiley, 2003.

Abstract

We report new ruthenium-catalyzed cis – trans isomerization of various functionalized epoxides. Enantiospecific isomerization of chiral epoxides is achieved without loss of enantiopurity, and epimerization occurs only at the epoxide carbon of the activating group.

Details

ISSN :
15222667 and 09317597
Volume :
34
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........004ea4b47af7bac731952906c5418461
Full Text :
https://doi.org/10.1002/chin.200328115