Quantitative in situ13C NMR studies of the electro-catalytic oxidation of ethanol

The identification and quantification of reaction intermediates and products in a time-resolved fashion is of great value for the understanding of mechanisms underlying the electro-catalytic oxidation of alcohols. Using a newly developed in situ cell, the identification of different intermediates, products, and side products became possible by monitoring the ethanol electro-oxidation in operando by 13C NMR spectroscopy.