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1-[(4-Chlorophenyl)(phenylimino)methyl]-7-methoxy-2-naphthol–1,4-diazabicyclo[2.2.2]octane (2/1)

Authors :
Noriyuki Yonezawa
Akiko Okamoto
Yuichi Kato
Ryosuke Mitsui
Atsushi Nagasawa
Source :
Acta Crystallographica Section E, Vol 66, Iss 10, Pp o2498-o2498 (2010)
Publication Year :
2010
Publisher :
International Union of Crystallography, 2010.

Abstract

In the crystal structure of the title cocrystal, 2C24H18ClNO2·C6H12N2, the 1,4-diazabicyclo[2.2.2]octane molecule is located on a twofold rotation axis and linked to the two triarylimine molecules by O—H...N hydrogen bonds, forming a 2:1 aggregate. C—H...Cl interactions are also observed. In the triarylimine molecule, the naphthalene ring system makes dihedral angles of 80.39 (6) and 82.35 (6)°, respectively, with the phenyl and benzene rings. The dihedral angle between these two latter rings is 87.09 (7)°.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
66
Issue :
10
Database :
OpenAIRE
Journal :
Acta Crystallographica Section E
Accession number :
edsair.doajarticles..84646c0da80a54f104ffe3c789c95371