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Chlorido[6-phenyl-4-(p-tolyl)-2,2′-bipyridyl-κ2N,N′]platinum(II)

Authors :
Hong Bo Lu
Guo Qiang Lv
Jia Xiang Yang
Jin Lin Zuo
Source :
Acta Crystallographica Section E, Vol 64, Iss 8, Pp m1013-m1013 (2008)
Publication Year :
2008
Publisher :
International Union of Crystallography, 2008.

Abstract

The asymmetric unit of the title compound, [Pt(C23H17N2)Cl], contains two independent molecules with distinct dihedral angles between the central pyridyl and methylbenzene rings [7.77 (2) and 24.07 (2)°]. Short intermolecular distances [3.582 (6) and 3.600 (6) Å] between the outer pyridine and the PtNC3 and PtN2C2 rings, respectively, indicate the existence of π–π interactions, which link the molecules into stacks along the a axis. The crystal structure is further stabilized by weak C—H...π interactions.

Subjects

Subjects :
Crystallography
QD901-999

Details

Language :
English
ISSN :
16005368
Volume :
64
Issue :
8
Database :
OpenAIRE
Journal :
Acta Crystallographica Section E
Accession number :
edsair.doajarticles..2396696d1603c5c4e7b20a0f2d2d1150