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Mild ArI-Catalyzed C(sp2)[BOND]H or C(sp3)[BOND]H Functionalization/C[BOND]O Formation: An Intriguing Catalyst-Controlled Selectivity Switch
- Source :
- Recercat. Dipósit de la Recerca de Catalunya, instname
- Publication Year :
- 2014
- Publisher :
- Wiley, 2014.
-
Abstract
- A tandem C(sp2)H and C(sp3)H functionalization/CO bond formation catalyzed by iodine(III) reagents generated in situ has been developed. The method shows wide scope under mild conditions and exhibits an unprecedented selectivity profile that can be switched depending on the catalyst employed.
- Subjects :
- metal-free
catalysis
site-selectivity
C-H functionalization
Subjects
Details
- Database :
- OpenAIRE
- Journal :
- Recercat. Dipósit de la Recerca de Catalunya, instname
- Accession number :
- edsair.dedup.wf.001..c5db24c3fe525f4b3013921549629124