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Preliminary Study of Epoxidation of Soybean Oil in Stirred Tank Reactor: the Effect of the Mixing Program

Authors :
Vianello, C.
Piccolo, D.
Maschio, G.
SALZANO, ERNESTO
Vianello, C.
Piccolo, D.
Salzano, E.
Maschio, G.
Source :
Chemical Engineering Transactions, Vol 57 (2017)
Publication Year :
2017
Publisher :
AIDIC Servizi S.r.l., 2017.

Abstract

Epoxidated vegetable oils are largely employed as plasticizer instead of harmful phthalates and they represent a sustainable choice to produce lubricants and intermediates. In this work, the epoxidation of soybean oil is carried using hydrogen peroxide (H2O2) 32wt.% and acetic acid instead of the commonly used H2O2 at 60wt.% and formic acid to reduce the risk of detonation and corrosion. The efficacy of an acid catalyst (sulfuric acid) is tested. Particular attention is focussed on a proper mixing program.

Details

Language :
English
ISSN :
22839216
Volume :
57
Database :
OpenAIRE
Journal :
Chemical Engineering Transactions
Accession number :
edsair.dedup.wf.001..a38598fb11fa76787d91a206ff89622a