Polymerization on unconventional substrates

Trabajo presentado en 20th Trends in Nanotechnology International Conference (2019), celebrada en San Sebastián (España), del 30 de septiembre al 4 de octubre de 2019
In the early 1900’s Fritz Ullmann first reported the synthesis of biaryls from aryl halides mediated by a fine copper powder1 , demonstrating with this the aromatic nucleophilic substitution mediated by copper, now known as Ullmann condensation reaction. More than hundred years after, this reaction is routinely used in numerous industrial applications and, nowadays it becomes widely used for the synthesis on metal surfaces of atomically precise graphene nanoribbons2 The next step to move toward device applications requires performing the synthesis directly on suitable substrates such as semiconducting, insulating or magnetic substrates. Whit in this context, in the present work we explore the Ullmann based synthesis of polymers on magnetic and insulating substrates. In particular we demonstrate the aryl homocoupling synthesis of 4,4-Dibromo (or diiodo)-p-terphenyl precursor into molecular poly-p-phenylene wires on the semiconductor TiO2 surface3 and on the bimetallic (and ferromagnetic) GdAu2 surface alloy4 . Moreover, we propose a reaction pathway during the polymerization. To monitor the chemical reaction complementary microscopic and spectroscopic surface science techniques (, scanning tunneling microscopy, X-ray photoemission spectroscopy, angle-resolved Photoemission spectroscopy) are used.