Effect of annealing on the thermoelectric properties of directionally grown Bi2Sr2Co.8Ox ceramics

The effect of annealing on directionally solidified Bi 2Sr 2Co 1.8O x ceramic rods has been studied for different times up to 1008 h. Microstructure has shown five different phases in the as-grown materials which have been reduced to two major ones after 1008 h thermal treatment, accompanied by an important grain growth. These microstructural changes are reflected on the mechanical properties which are higher than those measured in the as-grown materials in all cases. Moreover, they also produce an important decrease on the resistivity and increase of thermopower, leading to a raise on the power factor on thermally treated samples, about two times, compared to the as-grown samples. © 2012 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
The authors wish to thank the Gobierno de Aragón (Research Groups T12 and T87), the Spanish Ministry of Science and Innovation-FEDER (Project MAT2008-00429), and Universidad de Zaragoza (Project UZ2011-TEC-03) for financial support. The technical contributions of C. Estepa, J.A. Gómez and C. Gallego are also acknowledged. Sh. Rasekh acknowledges a JAE-PreDoc2010 grant from CSIC.