Chemismus paleofluid z ložisek typu 'orogenic gold': nové analytické přístupy a případové studie z Českého masívu

PALEOFLUID CHEMISTRY OF OROGENIC GOLD DEPOSITS: NOVEL ANALYTICAL METHODS AND CASE STUDIES FROM THE BOHEMIAN MASSIF Tomáš Hrstka1 1 Charles University in Prague, Faculty of Science, Institute of Geochemistry, Mineralogy and Mineral Resources, Albertov 6, Praha 2, CZ-128 43 Abstract of the Ph.D. Thesis Fluid inclusions represent a unique tool for understanding the processes leading to the formation of mineral deposits and fluid-rock interactions in general. Orogenic gold deposits in the central part of the Bohemian Massif (Libčice and Kasejovice deposits) were studied in order to provide a better understanding of their genesis. A multifaceted approach was adopted including a broad spectrum of micro-analytical methods. While traditional methods were used as the basis of this study (e.g., microthermometry, SEM and optical microscopy), the application and improvement/development of modern analytical methods (e.g., LA-ICP- MS and Raman spectroscopy) or introduction of alternative innovative techniques (CLSM, Nano- tomography, QEMSCAN) constituted a significant part of this study. This study reveals the importance of the HCO3 - species in hydrothermal fluids (i.e., >100 řC to ~350 řC). Previously, the prevalence of Cl- and other anions was reported for hydrothermal paleofluids and the majority of studies suggested...