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Tapes, sheets, and prisms. Identification of the weak C-F interactions that steer fullerene-porphyrin cocrystallization
- Source :
- Hosseini, A; Hodgson, MC; Tham, FS; Reed, CA; & Boyd, PDW. (2006). Tapes, sheets, and prisms. Identification of the weak C-F interactions that steer fullerene-porphyrin cocrystallization. Crystal Growth and Design, 6(2), 397-403. doi: 10.1021/cg050352n. UC Riverside: Retrieved from: http://www.escholarship.org/uc/item/1xc8d5gp, Crystal Growth and Design, vol 6, iss 2
- Publication Year :
- 2006
- Publisher :
- eScholarship, University of California, 2006.
-
Abstract
- Tetra(pentafluorophenyl)porphyrin (H2TPFPP) has been cocrystallized with C60 from arene solvents to give H 2TPFPP·C60, 1, H2TPFPP·C 60·8Benzene, 3, and 3H2TPFPP·2C 60·6Toluene, 4. Their X-ray structures have been determined to identify the supramolecular interactions that lead to tape, sheet, and prismatic packing motifs. In addition to close fullerene-porphyrin π-π interactions, attractive C-F⋯H-C interactions are important in connecting the C6F5 groups of one porphyrin to the pyrrole positions of a neighbor. This interaction is also seen in the structure of the free-base porphyrin H2TPFPP·3p-Xylene, 2. © 2006 American Chemical Society.
Details
- Language :
- English
- Database :
- OpenAIRE
- Journal :
- Hosseini, A; Hodgson, MC; Tham, FS; Reed, CA; & Boyd, PDW. (2006). Tapes, sheets, and prisms. Identification of the weak C-F interactions that steer fullerene-porphyrin cocrystallization. Crystal Growth and Design, 6(2), 397-403. doi: 10.1021/cg050352n. UC Riverside: Retrieved from: http://www.escholarship.org/uc/item/1xc8d5gp, Crystal Growth and Design, vol 6, iss 2
- Accession number :
- edsair.dedup.wf.001..13ed153c04ce578d36a8eef5b59e859a