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Stereoselective Synthesis of Axially Chiral N−C Bonds in N-Aryl Indoles
- Source :
- Organic Letters; March 2006, Vol. 8 Issue: 6 p1097-1100, 4p
- Publication Year :
- 2006
-
Abstract
- N-Aryl indoles with axially chiral N−C bonds were synthesized by stereoselective nucleophilic aromatic substitution reactions of planar chiral arene chromium complexes. Stereoselective chromium tricarbonyl migration was achieved in the sterically hindered N-aryl indole chromium complex by refluxing in toluene.
Details
- Language :
- English
- ISSN :
- 15237060 and 15237052
- Volume :
- 8
- Issue :
- 6
- Database :
- Supplemental Index
- Journal :
- Organic Letters
- Publication Type :
- Periodical
- Accession number :
- ejs8709226
- Full Text :
- https://doi.org/10.1021/ol0529997