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New Saccharinato/Ammonia Complexes of Nickel(II) and Zinc(II). A Structural and Spectroscopic Study
- Source :
- Zeitschrift für anorganische und allgemeine Chemie; March 2006, Vol. 632 Issue: 4 p619-623, 5p
- Publication Year :
- 2006
-
Abstract
- Two new saccharinate/NH3complexes of composition [Ni(sac)2(NH3)4] and [Zn(sac)2(NH3)2] were obtained and their crystal structures determined by single crystal X‐ray diffractometry. The elongated octahedral NiIIcomplex crystallizes in the monoclinic P21/c space group with Z = 2 whereas the tetrahedral ZnIIcomplex is triclinic (space group ${\rm P}{\bar 1}$and Z = 2). For [Ni(sac)2(NH3)4] the magnetic moment and electron absorption spectrum were obtained and discussed. The infrared spectra of both complexes were also recorded and briefly commented.
Details
- Language :
- English
- ISSN :
- 00442313 and 15213749
- Volume :
- 632
- Issue :
- 4
- Database :
- Supplemental Index
- Journal :
- Zeitschrift für anorganische und allgemeine Chemie
- Publication Type :
- Periodical
- Accession number :
- ejs8591330
- Full Text :
- https://doi.org/10.1002/zaac.200500471