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The Stereochemistry of Organometallic Compounds. XXXIV. Regioselection in the Hydroformylation of Silylalkenes

Authors :
Doyle, MM
Jackson, WR
Perlmutter, P
Source :
Australian Journal of Chemistry; 1989, Vol. 42 Issue: 11 p1907-1918, 12p
Publication Year :
1989

Abstract

The regiochemistry of hydroformylation of alkenes can be controlled by the use of bulky silyl groups attached to the alkene. Use of the t-butyldiphenylsilyl group leads to almost total regiocontrol and the method has been applied to the synthesis of aldols.

Details

Language :
English
ISSN :
00049425 and 14450038
Volume :
42
Issue :
11
Database :
Supplemental Index
Journal :
Australian Journal of Chemistry
Publication Type :
Periodical
Accession number :
ejs8411820
Full Text :
https://doi.org/10.1071/CH9891907