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Excess molar volumes of (dibutyl ether + trichloromethane or tetrachloromethane or 1,2-dichloroethane or 1,1,2-trichloroethane or 1,1,2,2-tetrachloroethane or pentachloroethane) at the temperature 303.15 K

Authors :
Singh, Jasbir
Joshi, I. M.
Sharma, S. C.
Source :
The Journal of Chemical Thermodynamics; September 1993, Vol. 25 Issue: 9 p1049-1054, 6p
Publication Year :
1993

Abstract

Excess molar volumes V<SUP>E</SUP><SUB>m</SUB> are reported for (dibutyl ether + trichloromethane or tetrachloromethane or 1,2-dichloroethane or 1,1,2-trichloroethane or 1,1,2,2-tetrachloroethane or pentachloroethane) at the temperature 303.15 K over the entire composition range by direct dilatometry. The curves of V<SUP>E</SUP><SUB>m</SUB> against mole fraction x are negative at all x for all the mixtures except for that with 1,2-dichloroethane in which case V<SUP>E</SUP><SUB>m</SUB> is positive. The excess volumes decrease in the sequences: 1,2-dichloroethane > tetrachloromethane > 1,1,2-trichloroethane > trichloromethane > 1,1,2,2-tetrachloroethane > pentachloroethane. Copyright 1993, 1999 Academic Press

Details

Language :
English
ISSN :
00219614 and 10963626
Volume :
25
Issue :
9
Database :
Supplemental Index
Journal :
The Journal of Chemical Thermodynamics
Publication Type :
Periodical
Accession number :
ejs832526
Full Text :
https://doi.org/10.1006/jcht.1993.1101