Ab InitioDetermination of the Novel Perovskite-Related Structure of La7Mo7O30from Powder Diffraction

A new mixed valence molybdate, La7Mo7O30, first prepared by high energy ball milling, has been successfully synthesized by controlled hydrogen reduction of La2Mo2O9. Its original crystal structure was determined from X-ray and neutron powder diffraction (space groupR3;a=b=17.0051(2) Å,c=6.8607(1) Å;Z=3; reliability factors:Rp=0.081,Rwp=0.091,χ2=3.1,RBragg=0.049,RF=0.033). It consists in the hexagonal stacking of individual cylinders of perovskite-type arrangement. These cylinders are built up from perovskite cages sharing corners in trans-position along their diagonal axis. Two different mixed-valence molybdenum sites coexist, with more (Mo+5.75) or less (Mo+4.5) distorted octahedral environments. Lanthanum atoms are located within the perovskite cages and around them, very close to their regular positions in the perovskite structure. Lanthanum and molybdenum atoms thus form two rows of almost perfect cubes, shifted from each other byc/2. An electron microscopy study revealed the defect-free cationic and octahedral arrangements in the (a,b) plane.