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Solvolytic routes to new nonabismuth hydroxy- and alkoxy-oxo complexes: synthesis, characterization and solid-state structures of novel nonabismuth polyoxo cations Bi9μ3-O8μ3-OR65R H, EtDedicated to Prof. Ian Rothwell, a leader in aryloxide and early transition metal chemistries.
- Source :
- Chemical Communications; 2005, Vol. 2005 Issue: 33 p4228-4230, 3p
- Publication Year :
- 2005
-
Abstract
- Base hydrolysis of BiOClO4 yields ClO4−salts of the novel nonabismuth polyoxo cation Bi9μ3-O8μ3-OH651; ethanolysis converts 1to the ethoxide Bi9μ3-O8μ3-OEt652.
Details
- Language :
- English
- ISSN :
- 13597345 and 1364548X
- Volume :
- 2005
- Issue :
- 33
- Database :
- Supplemental Index
- Journal :
- Chemical Communications
- Publication Type :
- Periodical
- Accession number :
- ejs7557314
- Full Text :
- https://doi.org/10.1039/b504864h