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Three‐Dimensionally Arranged NiSe2Nanosheets as an Efficient Electrocatalyst for Methanol Electrooxidation Reaction

Authors :
Ullah, Nabi
Guziejewski, Dariusz
Mahmood, Asim
Ullah, Sami
Khan, Sikandar
Hussain, Shahid
Imran, Muhammad
Source :
Energy Technology; September 2024, Vol. 12 Issue: 9
Publication Year :
2024

Abstract

Methanol oxidation stands out as a pivotal solution in addressing the global energy crisis and environmental pollution, owing to its practical applicability, high current density, and the ready availability of methanol as a fuel source. To effectively catalyze methanol oxidation, an electrocatalyst is imperious to overcome the activation energy barrier. Herein, a three‐dimensionally arranged NiSe2nanosheet‐based electrocatalyst is synthesized through a facile solvothermal followed by an annealing method. The catalyst's porous structure enhances catalytic efficiency by providing a substantial electrochemical surface area (ECSA) equivalent to 0.121 mF cm−2. Notably, the electrocatalyst exhibits a remarkable response of 21.58 mA cm−2at an overpotential of 1.70 V vs RHE, accompanied by the lowest Tafel slope recorded at 39.14 mV dec−1. The electronic circuit, represented by Rs(Qf(RfW(QdlRct)), aligns well with electrochemical impedance spectroscopy data, elucidating the reaction path and intrinsic properties. Furthermore, the catalytic performance is elucidated concerning ECSA and weight, revealing current densities of 5.60 mA cm−2and 71.34 mA mg−1, respectively. Impressively, the catalyst demonstrates exceptional resistance to poisoning and sustained stability over a continuous 3600‐s operation. This comprehensive study underscores the promising potential of the NiSe2nanosheet‐based electrocatalyst for efficient methanol oxidation, providing valuable insights for advancing clean energy technologies. The three‐dimensionally arranged NiSe2nanosheets are prepared via solvothermal followed by annealing method and applied for electrochemical methanol oxidation reaction and delivered good response.

Details

Language :
English
ISSN :
21944288 and 21944296
Volume :
12
Issue :
9
Database :
Supplemental Index
Journal :
Energy Technology
Publication Type :
Periodical
Accession number :
ejs67669763
Full Text :
https://doi.org/10.1002/ente.202400390