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Effect on pK<INF>a</INF> of Metal-Bound Water Molecules in Lanthanide Ion-Induced Cyclen Cavities
- Source :
- Organic Letters; December 2004, Vol. 6 Issue: 26 p4805-4808, 4p
- Publication Year :
- 2004
-
Abstract
- <UFIGR ID="ol048628sn00001">The macrocyclic cyclen conjugates <BO>1</BO>−<BO>4</BO> were synthesized with the aim of forming lanthanide ion-based macrocyclic conjugates possessing deep cavities, formed upon complexation to various lanthanide ions. These complexes all possess metal-bound water molecules, where the pK<INF>a</INF> of the water molecules depends on the nature of the cavity.
Details
- Language :
- English
- ISSN :
- 15237060 and 15237052
- Volume :
- 6
- Issue :
- 26
- Database :
- Supplemental Index
- Journal :
- Organic Letters
- Publication Type :
- Periodical
- Accession number :
- ejs6719220