Electrostatic Control of Nonlinear Photonic-Crystal Polaritons in a Monolayer Semiconductor

Integration of 2D semiconductors with photonic crystal slabs provides an attractive approach to achieving strong light–matter coupling and exciton–polariton formation in a chip-compatible geometry. However, for the development of practical devices, it is crucial that polariton excitations are easily tunable and exhibit a strong nonlinear response. Here we study neutral and charged exciton–polaritons in an electrostatically gated photonic crystal slab with an embedded monolayer semiconductor MoSe2and experimentally demonstrate a novel approach to optical control based on polariton nonlinearity. We show that spatial modulation of the dielectric environment within the photonic crystal unit cell results in the formation of two distinct excitonic species with significantly different nonlinear responses of the corresponding charged exciton–polaritons under optical pumping. This behavior enables optical switching with ultrashort laser pulses and can be sensitively controlled via an electrostatic gate voltage. Our results open new avenues toward the development of active polaritonic devices in a compact chip-compatible implementation.