The NO reduction by CO over NiOx/CeO2catalysts with a fixed Ni surface density: pretreatment effects on the catalyst structure and catalytic activityElectronic supplementary information (ESI) available. See DOI: https://doi.org/10.1039/d3cy01103h

NiOx/CeO2catalysts have shown promising results in various catalytic reactions, including the NO reduction by CO. In this study, we investigated the effect of oxidation and reduction treatments on the NO reduction by CO over pretreated NiOx/CeO2catalysts. A series of oxidized and reduced supported NiOxcatalysts were synthesized in two steps: (1) the pretreatment of CeO2supports at different temperatures (400, 500, and 700 °C) under oxidizing and reducing conditions and (2) the synthesis of NiOx/CeO2catalysts by an incipient wetness impregnation method (IWI) with a fixed surface density of 5.3 Ni per nm2under specific conditions (oxidation/reduction) applied during the CeO2treatment. The prepared catalysts were characterized viaBET, ICP/OES, Raman, XPS, and XRD to understand their physicochemical properties. The results showed that as the pretreatment temperature increased, the physicochemical properties of NiOx/CeO2catalysts were changed: a decreased specific surface area (SSA), decreased oxygen vacancy/defect sites, and an increased crystallite size. The oxidized NiOx/CeO2catalyst at a lower pretreatment temperature displayed a better catalytic activity, indicating that the physicochemical properties of the catalysts were key factors in enhancing the catalytic activity. To understand the intermediate species and reaction mechanism during the NO reduction by CO, an in situDRIFTS study was performed and a possible reaction mechanism was also discussed.