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Complexation of Alkali Chloride Contact Ion-Pairs Using A 2,5-Diamidopyrrole Crown Macrobicycle

Authors :
Mahoney, Joseph M.
Marshall, R. Andrew
Beatty, Alicia M.
Smith, Bradley D.
Camiolo, Salvatore
Gale, Philip A.
Source :
Journal of Supramolecular Chemistry; July 2001, Vol. 1 Issue: 4-6 p289-292, 4p
Publication Year :
2001

Abstract

A 2,5-diamidopyrrole-capped macrobicycle was synthesized and its chloride salt binding ability evaluated in polar and apolar organic solvents. X-ray crystal structures of the receptor and its sodium chloride complex were obtained and in the latter structure the salt is bound as a contact ion-pair.

Details

Language :
English
ISSN :
14727862
Volume :
1
Issue :
4-6
Database :
Supplemental Index
Journal :
Journal of Supramolecular Chemistry
Publication Type :
Periodical
Accession number :
ejs6520672
Full Text :
https://doi.org/10.1016/S1472-7862(02)00068-0