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New Types of Coupling Reactions of Some Nitriles on Ruthenium Complexes
- Source :
- Chemistry Letters; December 1997, Vol. 26 Issue: 12 p1243-1244, 2p
- Publication Year :
- 1997
-
Abstract
- A hydridoruthenium(II) complex [RuClH(CO)(PPh3)3] reacts with o-toluonitrile and water at 120 °C to give a novel five-membered cyclometallated complex, [Ru(C6H3MECH=NCH2C6H4Me-o)Cl(CO)(PPh3)2]. The hydrido complex reacts with benzoylacetonitrile at 80 °C to form a six-membered chelate complex, [RuCl{O=C(Ph)C(CN)=C(CH2COPh)NH}(CO)(PPh3)2].
Details
- Language :
- English
- ISSN :
- 03667022 and 13480715
- Volume :
- 26
- Issue :
- 12
- Database :
- Supplemental Index
- Journal :
- Chemistry Letters
- Publication Type :
- Periodical
- Accession number :
- ejs64674410
- Full Text :
- https://doi.org/10.1246/cl.1997.1243