Back to Search Start Over

Rate-Determining Electron Transfer from Allylic Grignard Reagents to Benzophenone

Authors :
Matsuyama, Toyoki
Yamataka, Hiroshi
Hanafusa, Terukiyo
Source :
Chemistry Letters; August 1988, Vol. 17 Issue: 8 p1367-1370, 4p
Publication Year :
1988

Abstract

The reactions of allyl magnesium bromide and crotyl magnesium bromide with benzophenone were determined to proceed via a rate-determining electron transfer mechanism by means of the isotope effect and substituent effect technique.

Details

Language :
English
ISSN :
03667022 and 13480715
Volume :
17
Issue :
8
Database :
Supplemental Index
Journal :
Chemistry Letters
Publication Type :
Periodical
Accession number :
ejs64672770
Full Text :
https://doi.org/10.1246/cl.1988.1367