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THE OXIDATION OF HYDROXYLAMINE BY FREMY’S SALT. PREPARATION OF N-NITROSAMINES AND TETRAZENES

Authors :
Tato, M P Vazaquez
Castedo, Luis
Riguera, Ricardo
Source :
Chemistry Letters; May 1985, Vol. 14 Issue: 5 p623-626, 4p
Publication Year :
1985

Abstract

Treatment of secondary amines with Fremy’s salt in aqueous sodium carbonate solution and in the presence of hydroxylamine gives a high yield of either N-nitrosamines or sym-tetrazenes. A mechanism for these conversions is proposed.

Details

Language :
English
ISSN :
03667022 and 13480715
Volume :
14
Issue :
5
Database :
Supplemental Index
Journal :
Chemistry Letters
Publication Type :
Periodical
Accession number :
ejs64658310
Full Text :
https://doi.org/10.1246/cl.1985.623