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INCOMPLETE CUBANE-TYPE SULFUR-CAPPED Mo3OS34+AQUA ION AND X-RAY STRUCTURE ANALYSIS OF Ba[Mo3OS3(HN(CH2CO2)2)3]·7H2O

Authors :
Shibahara, Takashi
Miyake, Hiroaki
Kobayashi, Kazuhiro
Kuroya, Hisao
Source :
Chemistry Letters; February 1986, Vol. 15 Issue: 2 p139-142, 4p
Publication Year :
1986

Abstract

A molybdenum(IV) aqua ion with sulfur bridges, Mo3OS34+, has been prepared and characterized. An X-ray structure analysis of the iminodiacetato complex prepared from the aqua ion has revealed the core structure of Mo3(μ-O)(μ-S)2(μ3-S).

Details

Language :
English
ISSN :
03667022 and 13480715
Volume :
15
Issue :
2
Database :
Supplemental Index
Journal :
Chemistry Letters
Publication Type :
Periodical
Accession number :
ejs64656561
Full Text :
https://doi.org/10.1246/cl.1986.139