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NOVEL ISOMERIZATION AND RETRO-MANNICH REACTION OF 1,1,2,2-TETRAACYLCYCLOPROPANES

NOVEL ISOMERIZATION AND RETRO-MANNICH REACTION OF 1,1,2,2-TETRAACYLCYCLOPROPANES

Authors :
Ohkata, Katsuo
Kubo, Yasuo
Tamaru, Akira
Hanafusa, Terukiyo
Source :
Chemistry Letters; August 1975, Vol. 4 Issue: 8 p859-862, 4p
Publication Year :
1975

Abstract

1,1,2,2-Tetraacylcyclopropanes (1a, 1b) were rearranged into nine-membered enol lactones (2a, 2b) by tertiary amines, while primary arylamines brought about retro-Mannich reaction to give bisdimedone (4) and Schiff base.

Details

Language :
English
ISSN :
03667022 and 13480715
Volume :
4
Issue :
8
Database :
Supplemental Index
Journal :
Chemistry Letters
Publication Type :
Periodical
Accession number :
ejs64653150
Full Text :
https://doi.org/10.1246/cl.1975.859