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BACKBONE REARRANGEMENT IN DOLABRADIENE

Authors :
Kitadani, Masayuki
Kabuto, Chizuko
Sakai, Kunikazu
Yoshikoshi, Akira
Kitahara, Yoshio
Source :
Chemistry Letters; September 1974, Vol. 3 Issue: 9 p963-966, 4p
Publication Year :
1974

Abstract

Upon heating in formic acid dolabradiene (1) gives a mixture of hydrocarbons. Five backbone rearrangement products isolated from the mixture are assigned to ?5(10)-8ß-rimuene (2), ?5(10)-rimuene (3), ?1(10)-rimuene (4), ?8(9)-pimaradiene (5), and ?1(10),5-rimutriene (6a), respectively. Their formation mechanisms are also discussed.

Details

Language :
English
ISSN :
03667022 and 13480715
Volume :
3
Issue :
9
Database :
Supplemental Index
Journal :
Chemistry Letters
Publication Type :
Periodical
Accession number :
ejs64652995
Full Text :
https://doi.org/10.1246/cl.1974.963